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作者:RUTH M LYNDEN-BELL , ANTHONY J STONE
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (7), pp.883-890
摘要:The environment of a solute molecule in an ionic liquid is likely to have large fluctuating electrostatic fields, and so the electrostatic properties of such a solute including its charge distribution and its polarizability may make a difference to both its static and dynamic pro...
作者:Neetu Kumari , M Ali Haider , Suddhastawa Basu
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (11), pp.1735-1740
摘要:Electrochemical performance of \(\hbox {La}_{0.8}\hbox {Sr}_{0.2}\hbox {MnO}_{3-\delta }\) (LSM) for \(\hbox {CO}_{2}\) reduction in solid oxide cell is studied by performing impedance spectroscopy measurement and current-voltage characterizations for varying ratio of \(\hbox {CO...
作者:Francesco Ricci , Pablo G Debenedetti
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (7), pp.801-823
摘要:A fundamental understanding of pure-component liquid-liquid phase separation in network-forming fluids remains an open challenge. While considerable progress has been recently made in demonstrating the existence of such a phase transition in some models via rigorous free ene...
作者:Mamoni Garai , Dhananjay Dey , Hare Ram Yadav ...
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (10), pp.1513-1520
摘要:A mononuclear cobalt(II) complex, [ \(\hbox {Co}\hbox {(phen)}_{2}\hbox {Cl}_{2}\) ], (phen = 1,10-phenanthroline) has been synthesized and structurally characterized by different spectroscopic methods including single crystal X-ray structural study. X-ray crystal structural anal...
作者:Yan-Fei Kang , Hai-Xia Qiao , Ya-Li Meng ...
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (8), pp.1219-1223
摘要:A fluorescent probe, with simplicity of structure and convenience of synthesis, is capable of detecting cysteine over other biothiols, such as homocysteine and glutathione. The detection limit of 60 nM and 190-fold increase in fluorescence intensity offer advantage for detection ...
作者:Yogeshwaran Krishnan , Allen Vincent , Manikandan Paranjothy
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (10), pp.1571-1577
摘要:Formation of simple organic species such as glycine in the interstellar medium and transportation to earth via meteorites is considered to be a possible route for ‘Origin of Life’ on earth. Glycine formation has been proposed to occur via two different pathways involving for...
作者:JUN TAO , XIAOFENG WANG
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (4), pp.495-503
摘要:Single crystals of β -Cyclotetramethylene tetranitramine (HMX) were prepared by the solvent evaporation method. The structure was then determined using infrared spectroscopy and single crystal X-ray diffraction. The modified attachment energy (AE) model was used to predict t...
作者:ATREYEE BANERJEE , MANOJ KUMAR NANDI , SARIKA MAITRA BHATTACHARYYA
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (7), pp.793-800
摘要:In this paper we explore the validity of the Rosenfeld and the Dzugutov relation for the Lennard-Jones (LJ) system, its repulsive counterpart, the WCA system and a network forming liquid, the NTW model. We find that for all the systems both the relations are valid at high tempera...
作者:Yongzhou Ye , Fei Shen , Hongning Wang ...
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (6), pp.765-774
摘要:A series of Mn/SSZ-13 catalysts of varying Mn content were synthesized by hydrothermal and co-precipitation methods. Their performances for the selective catalytic reduction (SCR) of \(\hbox {NO}_{\mathrm{x}}\) with \(\hbox {NH}_{3}\) were evaluated. The results indicate tha...
作者:Safa Ali-Asgari , Jafar Izadi Nia , Samira Zali
来源:[J].Journal of Chemical Sciences(IF 1.298), 2017, Vol.129 (8), pp.1319-1325
摘要:In this work, regioselectivity was investigated in the hetero-Diels–Alder reactions of styrenes (without substituent and with para-substituted groups) with 2-aza-1,3-butadiene from thermodynamic (Hammett study), electronic (HSAB criterion) and kinetic viewpoints. Furthermore...

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