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作者:Dr. Oleg A. Filippov , Dr. Antoine Bruneau‐Voisine ...
来源:[J].Angewandte Chemie International Edition(IF 13.734), 2019, Vol.58 (20), pp.6727-6731
摘要:Abstract(#br)Deprotonation of the MnI NHC‐phosphine complex fac‐[MnBr(CO)32P,C‐Ph2PCH2NHC)] ( 2 ) under a H2 atmosphere readily gives the hydride fac‐[MnH(CO)32P,C‐Ph2<...
作者:Dr. Boris Vabre , Dr. Yves Canac ...
来源:[J].Chemistry – A European Journal(IF 5.831), 2015, Vol.21 (48), pp.17403-17414
摘要:Abstract(#br)This contribution reports on a new family of NiII pincer complexes featuring phosphinite and functional imidazolyl arms. The proligands RPIMCHOPR′ react at room temperature with NiII precursors to give the c...
作者:Dr. Yves Canac
来源:[J].Chemistry – An Asian Journal(IF 4.572), 2018, Vol.13 (15), pp.1872-1887
摘要:Abstract(#br)The chemistry of carbeniophosphines and phosphoniocarbenes, which have general structures derived formally from the three‐component “carbene/phosphine/positive charge” association, is presented. These two complementary classes of carbon–phosphorus‐base...
作者:Dr. Christine Lepetit , Dr. Yves Canac ...
来源:[J].Chemistry – A European Journal(IF 5.831), 2010, Vol.16 (44), pp.13095-13108
摘要:Abstract(#br)Whereas the external nucleophilic reactivity of α‐amidiniophosphines has been previously illustrated by their complexation to transition‐metal centers, their internal electrophilic reactivity is herein investigated by using BIMIONAP (BIMIONAP=N‐methylated B...
作者:Dr. Christine Lepetit , Dr. Yves Canac ...
来源:[J].Chemistry – A European Journal(IF 5.831), 2012, Vol.18 (25), pp.7705-7714
摘要:Abstract(#br)Two types of imidazoliophosphane with additional electron‐withdrawing substituents, such as alkoxy or imidazolio groups, are experimentally described and theoretically studied. Diethyl N , N ′‐2,4,6‐methyl(phenyl)imidazoliophosphonite is shown to retain a P...
作者:Dr. Christine Lepetit , Carine Duhayon ...
来源:[J].Chemistry – A European Journal(IF 5.831), 2012, Vol.18 (50), pp.16153-16160
摘要:Abstract(#br)Carbene→chalcogenophosphenium adducts, which correspond to an intermolecular stabilization mode of the so far elusive, free oxo‐ and thiooxophosphenium species [R2P+ = X] (X=O, S) by imidazolylidene (NHC) and diaminocyclopropenylidene (BAC)...
作者:Dr. Ibrahim Abdellah , Carine Duhayon ...
来源:[J].ChemCatChem(IF 5.181), 2013, Vol.5 (10), pp.3014-3021
摘要:Abstract(#br)Pd‐catalyzed 5‐ exo ‐ trig or 6‐ endo ‐ trig CH oxidative cyclization of C ‐homoallyl‐ N ‐sulfonylhydrazones to 5‐vinylpyrazolines or 6‐methylidene‐1,4,5,6‐tetrahydropyridazines, respectively, is shown to be controlled in a highly selec...
作者:Dr. Christine Lepetit , Dr. Yves Canac ...
来源:[J].Chemistry – An Asian Journal(IF 4.572), 2014, Vol.9 (2), pp.462-465
摘要:Abstract(#br)A theoretical study of the enantiomerization pathway of BINAP, the paradigm of atropochiral ligands in asymmetric organometallic catalysis, is reported. Density functional theory was used with the B3PW91 functional and the 6‐31G(d,p) basis set. The calculation l...
作者:Dr. Oleg A. Filippov , Dr. Antoine Bruneau‐Voisine ...
来源:[J].Angewandte Chemie, 2019, Vol.131 (20), pp.6799-6803
摘要:Abstract(#br)Deprotonation of the MnI NHC‐phosphine complex fac‐[MnBr(CO)32P,C‐Ph2PCH2NHC)] ( 2 ) under a H2 atmosphere readily gives the hydride fac‐[MnH(CO)32P,C‐Ph2<...

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