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作者:L. Busetto , V. Zanotti , S. Bordoni ...
来源:[J].Journal of Cluster Science(IF 1.111), 1993, Vol.4 (1), pp.9-18
摘要:Abstract(#br)A large number of iron and ruthenium dinuclear complexes containing heteroatom substituted carbene ligands have been obtained by two different synthetic routes. The first method consists in reacting heteroatom substituted μ-carbyne cationic complexes with CN − ...
作者:Adriana I. Moncada , Joseph M. Tanski , LeGrande M. Slaughter
来源:[J].Journal of Organometallic Chemistry(IF 2), 2005, Vol.690 (24), pp.6247-6251
摘要:... In contrast, the use of isopropylisocyanide resulted in an unprecedented complex containing aminohydrazinocarbene ligands, which was characterized by X-ray crystallography. The latter complex represents a possible intermediate in the formation of chelating carbene ligands.
作者:Daniela I. Bezuidenhout , David C. Liles , Petrus H. van Rooyen ...
来源:[J].Journal of Organometallic Chemistry(IF 2), 2006, Vol.692 (4), pp.774-783
摘要:... Re, Y = S( 3 ), O( 4 )) were synthesised and characterised, giving axial carbene ligands for the dimanganese complexes, and equatorial carbene ligands for the dirhenium complexes. Aminolysis of these complexes with ammonia and n -propylamine yielded complexes [M 2 (CO) 9 {C(N...
作者:Luciano Canovese , Claudio Santo , Thomas Scattolin ...
来源:[J].Journal of Organometallic Chemistry(IF 2), 2015, Vol.794, pp.288-300
摘要:Abstract(#br)New palladacyclopentadiene compounds containing different chelate NHC-thioether and NHC-pyridine ligands have been prepared by transfer of the functionalized carbenes from the respective silver complexes to the polymeric precursors [PdC–COOR) 4 ] n (R = Me, t -Bu)...
作者:Frank Stiemke , Mimoza Gjikaj , Dieter E. Kaufmann
来源:[J].Journal of Organometallic Chemistry(IF 2), 2008, Vol.694 (1), pp.5-13
摘要:Abstract(#br)Synthesis of novel triphenylarsinyl-functionalized N -heterocyclic carbene pre-ligands starting from N,N -dimethylbenzylamine, chlorodiphenylarsine and different 1-substituted imidazoles and their characterization by NMR and X-ray analysis is reported. Furthermore, ...
作者:Shixian Zhao , Junshi Wu , Wanzhi Chen
来源:[J].Journal of Organometallic Chemistry(IF 2), 2017, Vol.848, pp.249-280
摘要:Abstract(#br)Heteroarene-linked bis( N -heterocyclic carbenes) constitute an important family of ligands in transition metal chemistry and homogeneous catalysis. These ligands are used as multidentate ligands for the construction of mononuclear and multinuclear complexes that sho...
作者:Luca Boselli , Isabelle Ader , Maëlle Carraz ...
来源:[J].European Journal of Medicinal Chemistry(IF 3.499), 2014, Vol.85, pp.87-94
摘要:Abstract(#br)New gold(I) complexes containing two 1-[2-(diethylamino)ethyl]imidazolydene ligands have been synthesized and characterized. The X-ray structures of two key compounds are presented. All complexes have been tested for their antiproliferative activities in prostate can...
作者:Normen Szesni , Christiane Hohberger , Gehad Genidy Mohamed ...
来源:[J].Journal of Organometallic Chemistry(IF 2), 2006, Vol.691 (26), pp.5753-5766
摘要:Abstract(#br)Heterocyclic carbene complexes are accessible from π-donor-substituted allenylidene complexes, [(CO) 5 Cr C C C(NMe 2 )Ph] ( 1 ) and [(CO) 5 Cr C C C(O- endo -Bornyl)OEt] ( 4 ), and various dinucleophiles by 1,2,3-diheterocyclization. The reaction of 1 with 1,2-dim...
作者:Luigi Busetto , Valerio Zanotti
来源:[J].Journal of Organometallic Chemistry(IF 2), 2005, Vol.690 (24), pp.5430-5440
摘要:Abstract(#br)The diiron frame Fe 2 Cp 2 CO 2 allows the coordination of a variety of carbene ligands, including heteroatom substituted (Fischer type) and alkylidenes, in both bridging and terminal coordination modes. Synthetic strategies have been devised for obtaining amino...
作者:Alison M Magill , David S McGuinness , Kingsley J Cavell ...
来源:[J].Journal of Organometallic Chemistry(IF 2), 2001, Vol.617, pp.546-560
摘要:Abstract(#br)Palladium complexes of functionalised heterocyclic carbene complexes have been synthesised. Treatment of imidazolium salts with Ag 2 O yields Ag I (carbene) 2 complexes, which act as carbene transfer agents when reacted with palladium salts. In this manner, [Pd(Me)...

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